Disulfonated Poly(arylene ether sulfone) Random Copolymers Containing Hierarchical Iptycene Units for Proton Exchange Membranes

A novel guanidinium grafted poly(aryl ether sulfone) for high-performance hydroxide exchange membranes.

A novel poly(aryl ether sulfone) ionomer containing hexaalkylguanidinium groups was synthesized, and membranes formed from this polymer displayed large ionic clusters, high hydroxide conductivity, and excellent solubility in low boiling point water-soluble solvents such as ethanol and methanol.

Phosphorus-Containing Sulfonated Polyimides for Proton Exchange Membranes

Synthesis and characterization of the novel sulfonated BAPPO monomer and its use in the synthesis of a new phosphine oxide-based sulfonated polyimide are described. BTDA, 6FDA, and DDS were used as monomers in the polyimide synthesis. Sulfonated polyimide membranes were obtained by a solution thermal imidization method. The thermal behavior of the polymers was investigated by DSC and TGA. The m...

Adsorption Properties of Thiol-Functionalized Silica Nanoparticles Prepared for Application in Poly(ether sulfone) Nanocomposite Membranes

An overview of organic/inorganic membranes based on sulfonated poly ether ether ketone for application in proton exchange membrane fuel cells

Nowadays, proton exchange membrane fuel cells (PEMFCs) are the most promising green energy conversion devices for portable and stationary applications. Traditionally, these devices were based onperfluoro-sulfonic acid electrolytes membranes, given the commercial name Nafion. Nafion is the mostused electrolyte membrane till now; because of its high electrochemical properties su...

Recent advances in sulfonated poly ( ether ether ketone ) based proton exchange membranes for high temperature fuel cells

Proton exchange membranes (PEMs) play an important role in the fuel cell systems. A good PEM must meet a series of requirements such as high proton conductivity, excellent mechanical strength and stability, chemical and electrochemical stability, low fuel crossover, etc. Nafion is currently the most commercially utilized electrolyte membranes for polymer electrolyte fuel cells, with high chemic...